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沈增明

 

热诚欢迎对有机化学感兴趣的研究生,博士后加入我们小组.

 

1、基本信息
姓名:沈增明
职称:副教授
电话:021-54748325 
邮箱:shenzengming@sjtu.edu.cn
通讯地址:上海市闵行区东川路800号上海交通大学建工楼312室

2、教育经历
2001-2006:中国科学院上海有机化学研究所,硕博。
导师:陆熙炎研究员

2006-2008:加拿大多伦多大学化学系,博士后。导师:Prof. Vy M. Dong 

3、工作经历
2010-至今:上海交通大学化学化工学院,副教授,硕士生导师

4、研究方向
1、金属催化的新型有机反应研究
2、金属催化的不对称反应的研究
3、杂环化合物的研究

5、科研项目
 铜催化的C—H键官能团化实现交叉偶联反应,国家自然科学基金委青年科学基金 (20902058),2010.01-2012.12,已结题。
 入选2009年度上海市浦江人才计划 (09PJ1408100), 2009.7-2011.7,已结题。
 惰性C-H键在廉价金属铜催化下的反应性研究,上海交通大学校长机动费研究基金,2011.1-2013.12。
 铜催化的C-C键断裂反应的研究,国家自然科学基金面上项目(21272001),2013.1-2016.12。
 铜催化的C-C键断裂反应的研究,上海市教委创新重点项目(13ZZ014),2013.1-2015.12。

6、荣誉奖励
1、2006年获“中科院研究生院优秀毕业生”称号
2、2009年获“上海市浦江人才计划”
3、2010年获上海交通大学“SMC-晨星青年学者奖励计划”优秀青年教师B类

7、教学工作
1、本科生:《有机化学》
2、研究生:《现代有机合成》

8、代表性论文
1.Kou, Xuezhen; Zhao, Mengdi; Qiao, Xixue; Zhu, Yamin; Tong, Xiaofeng; Shen, Zengming* “Copper-Catalyzed Aromatic C-H Bond Cyanation by C-CN Bond Cleavage of Inert Acetonitrile” Chem. Eur. J. 2013, 19, 16880-16886. (Highlighted as a frontispiece.)

2. Mo Song, Zhu Yamin, Shen Zengmging*, “Copper-catalyzed aromatic C–H bond halogenation with lithium halides under aerobic conditions” Org. Biomol. Chem. 2013, 11, 2756-2760. (Hot Paper, highlighted as a cover.)

3. Kou Xuezhen, Fan Jiajun, Tong Xiaofeng, Shen Zengming*, “Recent Progress in the Research of Transition-Metal-Catalyzed C—CN Bond Cleavage “ Chin. J. Org. Chem. 2013, 33, 1407-1422.

4. Shen, Zengming*; Ni, Zhenjie; Mo, Song; Wang, Jing; Zhu, Yamin; “Palladium-Catalyzed Intramolecular Decarboxylative Coupling of Arene Carboxylic Acids/Esters with Aryl Bromides” Chem. Eur. J.  2012, 18, 4859-4865.
5. Wang, Ruiping; Mo, Song; Lu, Yongzhong; Shen, Zengming*  "Domino Sonogashira Coupling /Cyclization Reaction Catalyzed by Copper and ppb Levels of Palladium: A Concise Route to Indoles and Benzo[b]furans" Adv. Synth. Catal. 2011,353, 713-718.
6. Lu, Yongzhong; Wang, Ruiping; Qiao, Xixue; Shen, Zengming* Copper-Catalyzed Aromatic C–H Bond Halogenation Using Lithium Halides as Halogenating Reagents, Synlett, 2011,1038. (Special Issue of Synlett dedicated to Professors Lu Xiyan and Dai Li-Xin)
7. Shen, Zengming; Dornan, Peter K.; Khan, Hasan A; Woo, Tom; Dong, Vy M. “Mechanistic insights into the rhodium-catalyzed intramolecular ketone hydroacylation” J. Am. Chem. Soc. 2009, 131, 1077-1091.
8. Shen, Zengming; Dong, Vy M. “Benzofurans prepared by C-H bond functionalization with acylsilanes” Angew. Chem. Int. Ed. 2009, 48, 784-786. (For a highlight,  see: Synfacts, 2009, 4, 409)
9. Shen, Zengming; Khan, Hasan A.; Dong, Vy M. “Rh-Catalyzed carbonyl hydroacylation: an enantioselective approach to lactones” J. Am. Chem. Soc. 2008, 130, 2916-2917. (See the highlight in Chemistry World featuring this work: James Mitchell Crow, "Rhodium fast tracks route to lactones." Editorial Board of SYNFACTS selects this article as the Synfact of the month, see: Synfacts, 2008, 5, 485).
10. Shen, Zengming; Lu, Xiyan “Cupric halide-mediated intramolecular halocyclization of N-electron-withdrawing group substituted 2-alkynylanilines for the synthesis of 3-haloindoles,” Adv. Synth. Catal. 2009, 351, 3107-3112.
11. Shen, Zengming; Khan, Hasan A.; Dong, Vy M. “Novel catalytic approach to chiral lactones”    235th ACS National Meeting, New Orleans, LA, United States, April 6-10, 2008.
12. Shen, Zengming; Lu, Xiyan; Lei, Aiwen. “Highly enantioselective hydrogenation of exocyclic double bond of N-tosyloxazolidinones catalyzed by a neutral rhodium complex and its synthetic applications” Tetrahedron 2006, 62, 9237-9246.
13. Shen, Zengming; Lu, Xiyan “Palladium(II)-catalyzed tandem intramolecular aminopalladation of alkynylanilines and conjugate addition for synthesis of 2,3-disubstituted indole derivatives”  Tetrahedron 2006, 62, 10896-10899.

 

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