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沈增明


热诚欢迎对有机化学感兴趣的博士、硕士研究生和博士后加入我们小组 (还有名额).


1、基本信息
姓名:沈增明
职称:教授
电话:021-54748325 
邮箱:shenzengming@sjtu.edu.cn
通讯地址:上海市闵行区东川路800号上海交通大学建工楼312室


2、教育经历
2001-2006:中国科学院上海有机化学研究所,硕博。
导师:陆熙炎院士

2006-2008:加拿大多伦多大学化学系,博士后。导师:Prof. Vy M. Dong


3、工作经历
2010-2018.1 上海交通大学化学化工学院,副教授

2018.1-至今 上海交通大学化学化工学院,教授, 博导 


4. 研究方向

1. 金属催化的C-C键和C-H键的活化

2. 金属催化的不对称反应的研究

3. 杂环化合物的研究,应用于药物和天然产物的合成


5、科研项目

1. 新型氰源的设计、合成及其在氰化反应中的应用,国家自然科学基金面上项目(21672144),2017.1-2020.12。(65万)

2. 铜催化的C-C键断裂反应的研究,国家自然科学基金面上项目(21272001),2013.1-2016.12。(80万)

3. 铜催化的C-H键官能团化实现交叉偶联反应,国家自然科学基金委青年科学基金(20902058), 2010.01-2012.12。(19万)

4. 铜催化的C-H键官能团化反应研究,国家自然科学基金委主任基金(20852004), 2009.01-2009.12。(10万)

5. 入选2009年度上海市浦江人才计划(09PJ1408100), 2009.7-2011.7。(20万)

6. 铜催化的C-C键断裂反应的研究,上海市教委科研创新重点项目(13ZZ014),2013.1-2015.12。(16万)

7. 荣获2010年度上海交通大学“SMC-晨星青年学者奖励计划”优秀青年教师(B类)(20万)

8. 惰性C-H键在廉价金属铜催化下的反应性研究,上海交通大学校长机动费研究基金,2011.1-2013.12。(30万)


6、荣誉奖励

1.首届上海交通大学“教书育人奖”提名奖(2017)

2.第二届上海高校青年教师教学竞赛“二等奖”(2016)

3.上海交通大学首届青年教师教学竞赛“一等奖”(2016)

4.上海交通大学教学能手称号(2016)

5.上海交通大学优秀教师“二等奖”(2016)

6.上海市浦江人才计划(2009)

7.上海交通大学“SMC-晨星青年学者奖励计划”优秀青年教师A类和B类(2017/2010)

8.2013年度三年聘期工作考核“优秀”

9.2016年和2017年教职工年度述职考核“优秀”

10.中科院研究生院优秀毕业生 (2006)


7、教学工作

热衷于本科生和研究生的教学工作,潜心教学研究。

本科生课程《有机化学》(专业基础课):64-68学时;承担了2010级,2013-2017级的教学任务。

研究生课程《现代有机合成》:36学时;承担了2010-2017级研究生的教学任务。

博士生课程《近代化学研究方法》:3学时;承担了2011-2017级的教学任务。


8、代表性论文

1. Li, Xiaomeng; Guo, Yunlong;Shen, Zengming* J. Org. Chem. 2018, 83, 2818.

2. Cruz, Faben A.+; Zhu, Yamin+; (并列一作,按字母顺序排列) Tercenio, Quentin D.;Shen, Zengming*,Dong, Vy M.* “Alkyne Hydroheteroarylation: nantioselective Coupling of Indolesand Alkynes via Rh-Hydride Catalysis”J. Am. Chem. Soc. 2017, 139, 10641-10644.

3. Zhu, Yamin;Shen, Zengming*“Copper-Catalyzed Acyloxycyanation of Alkynes with Acetonitrile: Regioselective Construction of Cyclic Acrylonitriles by 6-endo or 5-exo Cyclization” Adv. Synth. Catal. 2017, 359, 3515.

4. Lu, Wenkui; Xu Hui;Shen Zengming* “Copper-catalyzed aromatic C–H alkoxylation with alcohols under aerobic conditions” Org. Biomol. Chem., 2017,15, 1261–1267.

5. Yu, Zhengwei; Li, Linyi;Shen, Zengming*“Cu-Catalyzed Cyanation of Aryl Iodides with Acetonitrile as Cyano Source” Chin. J. Org. Chem. 2017,37, 1273-1277.

6. Zhang Wei; Yang, Shiping;Shen, Zengming* “Copper-Catalyzed Cyanomethylation of Substituted Tetrahydroisoquinolines with Acetonitrile” Adv. Synth. Catal. 2016,358, 2392 – 2397.

7. Zhao, Mengdi; Zhang, Wei;Shen, Zengming* “Cu-Catalyzed Cyanation of Indoles with Acetonitrile as a Cyano source” J. Org. Chem. 2015,80, 8868.

8. Li, Linyi; Yu, Zhengwei;Shen, Zengming*; “Copper-Catalyzed Aminoxylation of Different Types of Hydrocarbons with TEMPO: A Concise Route to N-Alkoxyamine Derivatives” Adv. Syn. Cat. 2015,357, 3495.

9. Zhu, Yamin; Li, Linyi;Shen, Zengming*“Cu-Catalyzed Cyanation of Arylboronic Acids with Acetonitrile: A Dual Role of TEMPO”Chem. Eur. J.2015,21, 13246.(Highlighted as a cover.)

10. Zhu, Yamin; Zhao, Mengdi; Lu, Wenkui; Li, Linyi;Shen, Zengming*“Acetonitrile as a Cyanating Reagent: Cu-Catalyzed Cyanation of Arenes” Org. Lett.2015,17, 2602. (Highlighted by Synform. See:Synform 2015, 10, A144–A145.)

11. Xu, Hui; Qiao, Xixue; Yang, Shiping;Shen, Zengming*“Cu-Catalyzed Direct Amidation of Aromatic C−H Bonds: An Access to Arylamines”J. Org. Chem.2014,79, 4414.

12. Kou, Xuezhen; Zhao, Mengdi; Qiao, Xixue; Zhu, Yamin; Tong, Xiaofeng;Shen, Zengming*“Copper-Catalyzed Aromatic C-H Bond Cyanation by C-CN Bond Cleavage of Inert Acetonitrile”Chem. Eur. J.2013, 19, 16880-16886. (Highlighted as a frontispiece.)

13. Mo Song, Zhu Yamin,Shen Zengmging*,“Copper-catalyzed aromatic C–H bond halogenation with lithium halides under aerobic conditions” Org. Biomol. Chem.2013,11, 2756-2760. (Hot Paper, highlighted as a cover.)

14. Kou Xuezhen, Fan Jiajun, Tong Xiaofeng,Shen Zengming*,“Recent Progress in the Research of Transition Metal-Catalyzed C-CN Bond Cleavage”Chin. J. Org. Chem.2013,33, 1407-1422.

15. Shen, Zengming*;Ni, Zhenjie; Mo, Song; Wang, Jing; Zhu, Yamin; “Palladium-Catalyzed Intramolecular Decarboxylative Coupling of Arene Carboxylic Acids/Esters with Aryl Bromides”Chem. Eur. J. 2012,18, 4859-4865.

16. Wang,Ruiping; Mo, Song; Lu, Yongzhong;Shen, Zengming*; “Domino Sonogashira Coupling/Cyclization Reaction Catalyzed by Copper and ppb Levels of Palladium: A Concise Route to Indoles and Benzo[b]furans”Adv. Synth. Catal. 2011,353, 713-718.

17. Lu,Yongzhong; Wang,Ruiping;Qiao,Xixue;Shen, Zengming*;“Copper-Catalyzed Aromatic C–H Bond Halogenation Using Lithium Halides as Halogenating Reagents”Synlett, 2011,1038. ( the special issue of Synlett dedicated to Professors Xiyan Lu and Li-Xin Dai).

18. Shen, Zengming; Dornan, Peter K.; Khan, Hasan A; Woo, Tom; Dong, Vy M.“Mechanistic Insights into the Rhodium-Catalyzed Intramolecular Ketone Hydroacylation” J. Am. Chem. Soc.2009,131, 1077-1091.

19. Shen, Zengming; Dong, Vy M. “Benzofurans Prepared by C-H Bond Functionalization with Acylsilanes”Angew. Chem. Int. Ed.2009,48, 784-786. (For a highlight, see: Synfacts, 2009, 4, 409)

20. Shen, Zengming; Khan, Hasan A.; Dong, Vy M.“Rh-Catalyzed Carbonyl Hydroacylation: An Enantioselective Approach to Lactones”J. Am. Chem. Soc.2008,130, 2916-2917.
• (See the highlight in Chemistry World featuring this work: James Mitchell Crow, "Rhodium fast tracks route to lactones." Editorial Board of SYNFACTS selects this article as the Synfact of the month, see: Synfacts, 2008, 5, 485).

21. Shen, Zengming; Lu, Xiyan; “Cupric Halide-Mediated Intramolecular Halocyclization ofN-Electron-Withdrawing Group-Substituted 2-Alkynylanilines for the Synthesis of 3-Haloindoles”Adv. Synth. Catal.2009,351, 3107-3112.

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