TOPIC： 金属有机活性中间体导向的催化反应及机理研究
SPEAKER： 黄汉民 研究员，兰州化学物理研究所
TIME：OCTOBER 9 (Friday) AM16:00
LOCATION：526 Fifth-floor Lecture Hall, Chemistry Building A (化学A楼526演讲厅)
INVITER： Prof. Wanbin Zhang (张万斌教授)
 

报告人简介：
黄汉民，男，1974年出生，研究员，博士生导师，羰基合成与选择氧化国家重点实验室常务副主任，所学术委员会委员。2003年于中科院大连化学物理研究所获得有机化学博士学位，2004年至2008年在日本名古屋大学物质科学国际研究中心从事博士后研究，期间获得JSPS-Fellow基金支持。2008年4月起在兰州化学物理研究所开始从事独立研究工作，建立了有机合成研究小组，并入选中科院“百人计划”。主要研究领域为导向有机合成的金属有机化学研究，在不对称催化和惰性键的选择性活化方面开展研究工作。近年来，作为第一作者或通讯作者已在Chem. Rev; J. Am. Chem. Soc.; Angew. Chem. Int. Ed.; Chem. Eur. J.；Org. Lett.；Chem.Comm.; J. Org. Chem.等刊物上发表研究论文70多篇，其中SCI-I区(IF>10)共15篇，被引用1500多次。授权中国专利2项，美国专利1项,日本专利1项；申请中国专利10多项。相关研究工作分别被美国化学会的《化学与工程新闻》(Chemical & Engineering News)、《自然》(Nature)期刊的子刊（Nature Chemical Biology）、专业评论期刊Synform和Synfacts作为亮点进行评论和转载。2012年获得国家自然科学基金“优秀青年基金”的资助，2013年中科院“百人计划”结题为优秀，并获得第二届中国均相催化青年奖，2015年度中国科学院优秀研究生指导教师奖。

代表论文

1,Guiping Qin, Lixin Li, Jiawen Li, and Hanmin Huang*, Palladium-Catalyzed Formal Insertion of Carbenoids into Aminals via C-N Bond Activation, J. Am. Chem. Soc. 2015, 137, DOI: 10.1021/jacs.5b08476, ASAP.
2,Hui Yu, Guoying Zhang, and Hanmin Huang*, Palladium-Catalyzed Dearomative Cyclocarbonylation via C-N Bond Activation, Angew. Chem. Int. Ed. 2015, 54, 10912-10916.
3,Guoying Zhang, Bao Gao, and Hanmin Huang*, Palladium-Catalyzed Hydroaminocarbonylation of Alkenes with Amines: A Strategy to Overcome Basicity-Barrier Imparted by Aliphatic Amines, Angew. Chem. Int. Ed. 2015, 54, 7657-7661.
4,Yinjun Xie, Shengmei Guo, Longmin Wu, Chungu Xia, and Hanmin Huang*, Metal Bridging for Directing and Accelerating Electron Transfer as Exemplified by Harnessing the Reactivity of AIBN, Angew. Chem. Int. Ed. 2015, 54, 5900-5904.
5,Lei Yang, and Hanmin Huang*, Transition-Metal-Catalyzed Direct Addition of Unactivated C−H Bonds to Polar Unsaturated Bonds, Chem. Rev. 2015, 115, 3468-3517.
6,Jianhua Hu, Yinjun Xie, and Hanmin Huang*, Palladium-Catalyzed Insertion of an Allene into an Aminal: Aminomethylamination of Allenes via C-N Bond Activation, Angew. Chem. Int. Ed. 2014. 53, 7272-7276.
7,Yinjun Xie, Jianhua Hu, Pan Xie, Bo Qian, and Hanmin Huang*, Palladium-Catalyzed Difunctionalization of Enol Ethers to Amino Acetals with Aminals and Alcohols, J. Am. Chem. Soc. 2013, 135, 18327-18330.
8,Guoying Zhang, Lei Yang, Yanyu Wang, Yinjun Xie, and Hanmin Huang*, An Efficient Rh/O2 Catalytic System for Oxidative C-H Activation/Annulation: Evidence for Rh(I) to Rh(III) Oxidation by Molecular Oxygen, J. Am. Chem. Soc. 2013, 135, 8850-8853.
9,Yinjun Xie, Jianhua Hu, Yanyu Wang, Chungu Xia, and Hanmin Huang*, Palladium-Catalyzed Vinylation of Aminals with Simple Alkenes: A New Strategy to Construct Allylamines. J. Am. Chem. Soc. 2012, 134, 20613-20616.
10,Pan Xie, Yinjun Xie, Bo Qian, Han Zhou, Chungu Xia, and Hanmin Huang*, Palladium-Catalyzed Oxidative Carbonylation of Benzylic C-H Bonds via Nondirected C(sp3)-H Activation. J. Am. Chem. Soc. 2012, 134, 9902-9905.
11,Dengjian Shi, Yinjun Xie, Han Zhou, Chungu Xia, and Hanmin Huang*, A Highly Diastereo- and Enantioselective Reaction for Constructing Functionalized Cyclohexanes: Six Contiguous Stereocenters in one Step. Angew. Chem. Int. Ed. 2012, 51, 1248-1251. (Highlight by Chemical & Engineering News、Nature Chemical Biology和Synform).
12,Yinjun Xie, Yingwei Zhao, Bo Qian, Lei Yang, Chungu Xia, and Hanmin Huang*, Enantioselective N-H Functionalization of Indole with α,β-Unsaturated γ-Lactams Catalyzed by Brønsted Acids. Angew. Chem. Int. Ed. 2011, 50, 5682-5686. (Highlight by Synfacts, 同时被评为2011年Angew. Chem. Int. Ed.下载量最多的25篇之一，排在第9位)。
13,Shengmei Guo, Yinjun Xie, Xinquan Hu, Chungu Xia, and Hanmin Huang*, Diastereo- and Enantioselective Catalytic Tandem Michael Addition/Mannich Reaction: Access to Chiral Isoindolinones and Azetidines with Multiple Stereocenters. Angew. Chem. Int. Ed. 2010, 49, 2728-2731.( Highlight by Synfacts).
14,Bo Qian, Shengmei Guo, Jianping Shao, Qiming Zhu, Lei Yang, Chungu Xia*, and Hanmin Huang*, Palladium-Catalyzed Benzylic Addition of 2-Methyl Azaarenes to N-Sulfonyl Aldimines via C-H Bond Activation. J. Am. Chem. Soc. 2010, 132, 3650-3651.
15,Hanmin Huang, Tomoko Okuno, Kazuomi Tsuda, Masahiro Yoshimura, Masato Kitamura* “Enantioselective Hydrogenation of Aromatic Ketones Catalyzed by Ru Complexes of Goodwin-Lions-type sp2N/sp3N hybrid Ligands R-BINAN-R΄-Py” J. Am. Chem. Soc. 2006, 128, 8716-8717.