【20th Nov.】Water-Based Reactions: A 20-Year Journey
日期：2014-11-20
阅读：902
TITLE：Water-Based Reactions: A 20-Year Journey
SPEAKER：罗德平教授，南洋理工大学（新加坡），中科大千人计划
TIME：Thursday, November 20, 15:00p.m.
ROOM：410Meeting Room HUAXUE B BUILDING (化学B楼410会议室)
INVITER： 张万斌教授 (化学化工学院)
Water-Based Reactions: A 20-Year Journey
Loh Teck-Peng1,2*
1Division of Chemistry & Biological Chemistry, Nanyang Technological University,
50 Nanyang Avenue, Singapore 639798.
2Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, 230026 (P. R. China)
E-mail: teckpeng@ntu.edu.sg
Abstract: The use of water as a solvent in organic reactions offers various advantages from the point of view of Green Chemistry. This talk focuses on the results of a 20-year journey in the development of various water-stable organometallics1, water-tolerate Lewis acids2 and metal-free systems3 and their applications in the synthesis of natural products and drugs as well as biomolecules functionalizations.
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References
① a) Shen, Z.-L.; Wang, S.-Y.; Chok, Y.-K.; Xu, Y.-H.; Loh, T.-P. Chem. Rev. 2013, 113, 271-401; b) Shen, Z. L.; Goh, K. K. K.; Cheong, H. L.; Wong, C. H. A.; Lai, Y. C.; Yang, Y. S.; Loh, T. P. J. Am. Chem. Soc. 2010, 132, 15852; c) Loh, T.-P.; Tan, K.-T.; Chng, S.-S.; Cheng, H.-S. J. Am. Chem. Soc. 2003, 125, 2958.
② a) Loh, T.-P.; Chua, G.-L. Chem. Commun. 2006, 2739-2749; b) T.-P. Loh and X.-R. Li, Angew. Chem., Int. Ed. Engl. 1997, 36, 980.
③ a) Abbas, A.; Xing, B.; Loh, T.-P. Angew. Chem. Int. Ed. 2014, 53, 7491-7494; b) Alam, J.; Keller, T. H.; Loh, T. P. J. Am. Chem. Soc. 2010, 132, 9546-9548.
