李新昊教授

电子邮件:xinhaoli@sjtu.edu.cn
通讯地址:上海市东川路800号化学C楼

  • 教育背景

    1999-2003:吉林大学化学院,学士
    2004-2009:吉林大学化学院,博士
    2009-2012:德国马普所胶体界面所,博士后(洪堡学者)

  • 工作经历

    2013-至今:上海交通大学化学化工学院,特别研究员、教授

    2016-2021:德国马普协会-上海交通大学国际伙伴小组,Group leader

  • 研究方向

    发展电子界面催化材料(EIC),着手从小分子直接合成的策略从原子、分子水平构筑活性中心及界面结构,以期实现界面电子整流对催化活性中心的效率、选择性和稳定性的全面提升,拓展电子界面催化材料在有机合成、光催化、电催化等催化重要领域的应用。

  • 科研项目

    承担国家自然科学基金、上海市科委/教委、德国马普协会国际伙伴小组等多个项目

  • 代表性论文专著

    21. X. Lin, Z. Zhou, Q. Y. Li, D. Xu, S. Y. Xia, B. L. Leng, G. Y. Zhai, S. N. Zhang, L. H. Sun, G. Zhao*, J. S. Chen, X. H. Li* “Direct Oxygen Transfer from H2O to Cyclooctene over Electron-Rich RuO2 Nanocrystals for Epoxidation and Hydrogen Evolution” 

    Angew. Chem. Int. Ed., 2022, 61, e202207108.

    20. D. Xu, X. Lin, Q. Y. Li, S. N. Zhang, S. Y. Xia, G. Y. Zhai, J. S. Chen, X. H. Li* “Boosting mass exchange between Pd/NC and MoC/NC dual junctions via electron exchange for cascade CO2 fixation” 

    J. Am. Chem. Soc., 2022, 144, 5418–5423.

    19. L. H. Sun, Q. Y. Li, S. N. Zhang; D. Xu, Z. H. Xue, H. Su, X. Lin, G. Y. Zhai, P. Gao, S. I. Hirano, J. S. Chen, X. H. Li* “Heterojunction-based electron donators to stabilize and activate ultrafine Pt nanoparticles for efficient hydrogen atom dissociation and gas evolution” 

    Angew. Chem. Int. Ed., 2021, 60, 25766–25770.

    18. P. Gao, Z. H. Xue, S. N. Zhang; D. Xu, G. Y. Zhai, Q. Y. Li, J. S. Chen, X. H. Li* “Schottky barrier-induced surface electric field boosts universal reduction of NOx- in water to ammonia” 

    Angew. Chem. Int. Ed., 2021, 60, 20711–20716 (Hot Paper).

    17. X. Lin, S. N. Zhang, D. Xu, J. J. Zhang, Y. X. Lin, Y. Zhai, H. Su, Z. H. Xue, X. Liu, M. Antonietti, J. S. Chen, X. H. Li* “Electrochemical activation of C–H by electron-deficient W2C nanocrystals for simultaneous alkoxylation and hydrogen evolution”

    Nat. Commun. 2021, 12, 3882.

    16. Z. H. Xue, S. N. Zhang, Y. X. Lin, H. Su, G. Y. Zhai, J. T. Han, Q. Y. Yu, X. H. Li*, M. Antonietti, J. S. Chen “Electrochemical Reduction of N2 into NH3 by Donor-Acceptor Couples of Ni and Au Nanoparticles with a 67.8% Faradaic Efficiency”

    J. Am. Chem. Soc. 2019, 141, 14976–14980.

    15. Y. X. Liu, H. H. Wang, T. J. Zhao, B. Zhang; H. Su, Z. H. Xue, X. H. Li*, J. S. Chen* “Schottky Barrier Induced Coupled Interface of Electron-Rich N-Doped Carbon and Electron-Deficient Cu: In-Built Lewis Acid-Base Pairs for Highly Efficient CO2 Fixation”

    J. Am. Chem. Soc. 2019, 141, 38–41.

    14. Y. X. Lin, S. N. Zhang, Z. H. Xue, J. J. Zhang, H. Su, T. J. Zhao, G. Y. Zhai, X. H. Li*, M. Antonietti, J. S. Chen* “Boosting Selective Nitrogen Reduction to Ammonia on Electron-Deficient Copper Nanoparticles”

    Nat. Commun. 2019, 10, 4830.

    13. H. Su, P. Gao, M. Y. Wang, G. Y. Zhai, J. J. Zhang, T. J. Zhao, J. Su, X. H. Li*, M. Antonietti, J. S. Chen* “Grouping Effect of Single Nickel−N4 Sites in Nitrogen-Doped Carbon Boosts Hydrogen Transfer Coupling of Alcohols and Amines”

    Angew. Chem. Int. Ed. 2018, 57, 15194–15198 (VIP Paper).

    12. Y. X. Lin, W. J. Feng, J. J. Zhang, Z. H. Xue, T. J. Zhao, H. Su, S. I. Hirano, X. H. Li*, J. S. Chen “Polyimide nanolayer as metal-free and durable organic electrode toward highly efficient oxygen evolution”

    Angew. Chem. Int. Ed. 2018, 57, 12563–12566.

    11. Z. H. Xue, J. T. Han, W. J. Feng, Q. Y. Yu, X. H. Li*, M. Antonietti, J. S. Chen*, “Tuning the Adsorption Energy of Methanol Molecules Along Ni-N-Doped Carbon Phase Boundaries by the Mott–Schottky Effect for Gas-Phase Methanol Dehydrogenation”

    Angew. Chem. Int. Ed. 2018, 57, 2697-2701.

    10. H. Su, K. X. Zhang,, B. Zhang, H. H. Wang, Q. Y. Yu, X. H. Li*, M. Antonietti, J. S. Chen, “Activating cobalt nanoparticles via the Mott-Schottky effect in nitrogen-rich carbon shells for base-free aerobic oxidation of alcohols to esters” 

    J. Am. Chem. Soc. 2017, 139, 811-818.

    9. T. L. Cui, W. Y. Ke, W. B. Zhang, H. H. Wang, X. H. Li*, J. S. Chen* “Encapsulating Palladium Nanoparticles Inside Mesoporous MFI Zeolite Nanocrystals for Shape-Selective Catalysis”

    Angew. Chem. Int. Ed. 2016, 55, 9178–9182.

    8. L. B. Lv, T. L. Cui, B. Zhang, H. H. Wang, X. H. Li*, J. S. Chen* “Wrinkled graphene monoliths as superabsorbing building blocks for superhydrophobic or superhydrophilic surfaces”

    Angew. Chem. Int. Ed. 2015, 54, 15165–15169.

    7. T. N. Ye, L. B. Lv, X. H. Li*, M. Xu, J. S. Chen*, “Strongly-veined Carbon “Nanoleaves” as Highly Efficient Metal-free Electrocatalyst”

    Angew. Chem. Int. Ed. 2014, 53, 6905–6909.

    6. Y. Y. Cai, X. H. Li*, Y. N. Zhang, X. Wei, K. X. Wang, J. S. Chen*, “Highly Efficient Dehydrogenation of Formic Acid over a Palladium-Nanoparticle-Based Mott–Schottky Photocatalyst”

    Angew. Chem. Int. Ed. 2013, 52, 11822–11825.

    5. X. H. Li*, M. Antonietti, “Polycondensation of Boron- and Nitrogen-Codoped Holey Graphene Monoliths from Molecules: Carbocatalysts for Selective Oxidation”

    Angew. Chem. Int. Ed. 2013, 52, 4572-4576.
    4. X. H. Li*, M. Antonietti, “Metal Nanoparticles Inside Mesoporous N-doped Carbons and Carbon Nitride: Functional Mott-Schottky Heterojunctions for Catalysis”

    Chem. Soc. Rev. 2013, 42, 6593 - 6604.
    3. X. H. Li*, S. Kurasch, U. Kaiser, M. Antonietti*, “Synthesis of Monolayer-Patched Graphene from Glucose”

    Angew. Chem. Int. Ed. 2012, 51, 9689-9692 (VIP paper).

    2. X. H. Li*, J. S. Chen, X. C. Wang, J. H. Sun, M. Antonietti, “Metal-Free Activation of Dioxygen by Graphene/g-C3N4 Nanocomposites: Functional Dyads for Selective Oxidation of Saturated Hydrocarbons”

    J. Am. Chem. Soc. 2011, 133, 8074-8077.
    1. X. H. Li, D. H. Zhang, J. S. Chen*, “Synthesis of Amphiphilic Superparamagnetic Ferrite/Block Copolymer Hollow Submicrospheres”

    J. Am. Chem. Soc. 2006, 128, 8382-8383.

  • 教学工作

    本科生《固体化学》《ET中心创新实验》

    研究生《材料化学》

  • 人才需求

    欢迎报考硕士、博士研究生及博士后!

地址:上海市东川路800号 200240
电话:021-54742893
E-mail:sjtuscce@sjtu.edu.cn

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