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张兆国

 

1、基本信息
姓名:张兆国
职称:教授
电话:021-54748925 
邮箱:zhaoguo@sjtu.edu.cn
主页:zhaoguo.sjtu.edu.cn
通讯地址:上海市东川路800号化学化工学院B楼526室

2、教育经历
1987-1991:山东大学化学系,学士
1991-1994:南京大学化学学院,硕士
1994-1997:中国科学院上海有机化学研究所,博士
1997-2000:美国宾夕法尼亚州立大学化学系,博士后

3、工作经历
2000-2005:中国科学院上海有机化学研究所,研究员
2005-至今:上海交通大学化学与化工学院,教授

4、研究方向
1、金属有机化学与不对称催化
2、精细有机合成
3、可见光条件下的催化反应

5、科研项目
主持和参加国家自然科学基金项目、中国科学院基金项目、国家重点实验室开放基金项目和国际、国内企业合作项目。

6、荣誉奖励
1、2000年获中国科学院百人计划
2、2002年获上海市“科技启明星”
3、2004年被评为中国科学院优秀研究生导师2
4、2006年获得美国Eli Lilly Research Excellence Award
5、2007年获上海市曙光学者

7、学术兼职
美国化学会会员

8、教学工作
1、本科生:《有机合成》、
2、研究生:《高等有机合成》

9、代表性论文及专著
论文
1. Zhang, L.; Xie, X.; Fu, L.; Zhang, Z. “[RuCl2(p-cymene)]2-Catalyzed Conjugate Addition of Arylboronic Acids to α,β-Unsaturated Ketones under Ligand-Free and Neutral Conditions” J. Org. Chem. 2013, 78, 3434-3437.
2. Ren, K.; Zhang, L.; Hu, B.; Zhao, M.; Tu, Y.; Xie, X.; Zhang, T. Y.; Zhang, Z. “Cationic-Rhodium-Catalyzed Kinetic Resolution of Allylic Alcohols through a Redox Isomerization Reaction in a Noncoordinating Solvent” ChemCatChem 2013, 5, 1317-1320.
3. Tao, X.; Li, W.; Li, X.; Xie, X.; Zhang, Z. “Diastereo- and Enantioselective Asymmetric Hydrogenation of α-Amido-β-keto Phosphonates via Dynamic Kinetic Resolution” Org. Lett. 2013, 15, 72-75.
4. Li, W.; Tao, X.; Ma, X.; Fan, W.; Li, X.; Zhao, M; Xie, X.; Zhang, Z. “Ru-Catalyzed Asymmetric Hydrogenation of 3-Oxoglutaric Acids Derivatives: Study on the Unconventional Solvent and Substituent Effects” Chem. Eur. J. 2012, 18, 16531-16539.
5. Tao, X.; Li, W.; Ma, X.; Li, X.; Fan, W.; Zhu, L.; Xie, X.; Zhang, Z. “Enantioselective Hydrogenation of β Ketophosphonates with Chiral Ru(II) Catalysts” J. Org. Chem. 2012, 77, 8401-8409.
6. Ma, F.; Xie, X.; Zhang, L.; Peng, Z.; Ding, L.; Fu, L.; Zhang, Z. “Palladium-Catalyzed Amidation of Aryl Halides Using 2-Dialkylphosphino- 2′-alkoxyl-1,1′-binaphthyl as Ligands”, J. Org. Chem., 2012, 77, 5279–5285.
7. Jackowski, O.; Wang, J.; Xie,X.; Ayad, T.; Zhang, Z.; Ratovelomanana-Vidal, V. Enantioselective Rhodium-Catalyzed Synthesis of α-Chloromethylene-γ- Butyrolactams from N-Allylic Alkynamides, Enantioselective Synthesis of 1-Aryl-tetrahydroisoquinolines through Iridium Catalyzed Asymmetric Hydrogenation, Org. Lett. 2012, 14, 3308.
8. Berhal, F.; Wu, Z.; Zhang, Z.; Ayad, T.; Ratovelomanana-Vidal V. “Enantioselective Synthesis of 1-Aryl-tetrahydroisoquinolines through Iridium Catalyzed Asymmetric Hydrogenation” Org. Lett. 2012, 14, 4006.
9. Li, W.; Fan, W.; Ma, X.; Tao, X.; Li, X.; Xie, X.; Zhang, Z. “Ru-catalyzed hydrogenation of 3,5-diketo amides: simultaneous control of chemo- and enantioselectivity” Chem. Commun. 2012, 48, 8976.
10. Ma, X.; Li, W.; Li, X.; Tao, X.; Fan, W.; Xie, X.; Ayad, T.; Vidal, V.; Zhang, Z. “Ru-catalyzed highly chemo- and enantioselective hydrogenation of -halo- -unsaturated--keto esters under neutral conditions” Chem. Commun. 2012, 48, 5352.
11. Fan, W.; Li, W.; Ma, X.; Tao, X.; Li, X.; Yao, Y.; Xie, X.; Zhang, Z. “Acid-labile -ketal--hydroxy esters by asymmetric hydrogenation of corresponding -ketal--keto esters in the presence of CaCO3” Chem. Commun. 2012, 48, 4247.
12. Li, W.; Xie, X.; Tao, X.; Ma, X.; Fan, W.; Li, X.; Zhang, Z. “RuCl2(PPh3)3-catalyzed chemoselective hydrogenation of -diketo acid derivatives at the -carbonyls” RSC Adv.. 2012, 2, 3214.
13. Tao, X.; Li, W.; Ma, X.; Li, X.; Fan, W.; Xie, X.; Ratovelomanana-Vidal, V.; Ayad, T.; Zhang, Z. J. Org. Chem. 2012, 77, 612.
14. Yang, Y.; Chen, L.; Zhang, Z.; Zhang Y. “Palladium-Catalyzed Oxidative C−H Bond and C═C Double Bond Cleavage: C-3 Acylation of Indolizines with α,β-Unsaturated Carboxylic Acids” Org. Lett. 2011, 13, 1342.
15. Fan, W.; Li, W.; Ma, X.;Tao, X.; Li, X.; Yao, Y.; Xie, X.; Zhang, Z. “Ru-Catalyzed Asymmetric Hydrogenation of γ-HeteroatomSubstituted β-Keto Esters ” J. Org. Chem. 2011, 76, 9445.
16. Li, W.; Ma, X.; Fan, W.; Tao, X.; Li, X.; Xie, X.; Zhang, Z. “Ru-Catalyzed Asymmetric Hydrogenation of 3-Oxoglutaric Acid Derivatives via Solvent-Assisted Pinpoint Recognition of Carbonyls in Close Chemical Propinquity” Org. Lett. 2011, 13, 3876.
17. Yao, Y.; Fan, W.; Li, X.; Ma, X.; Zhu, L.; Xie, X. “Synthesis of (S)-7-Amino-5-azaspiro[2.4]heptane via Highly Enantioselective Hydrogenation of Protected Ethyl1-(2-Aminoaceto)cyclopropanecarboxylates” J. Org. Chem. 2011, 76, 2807.

 


 

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